Experiments into nuclear structure have found that the total mass of a nucleus is?less?than the sum of the masses of its constituent nucleons
This difference in mass is known as the?mass defect
Mass defect is defined as:
The difference between an atom's mass and the sum of the masses of its protons and neutrons
The mass defect Δm of a nucleus can be calculated using:
Δm = Zmp?+ (A – Z)mn?– mtotal
Where:
Z = proton number
A = nucleon number
mp?= mass of a proton (kg)
mn?= mass of a neutron (kg)
mtotal?= measured mass of the nucleus (kg)
A system of separated nucleons has a greater mass than a system of bound nucleons
Due to the equivalence of mass and energy, this decrease in mass implies that energy is released in the process
Since nuclei are made up of neutrons and protons, there are forces of repulsion between the positive protons
Therefore, it takes energy, ie. the binding energy, to hold nucleons together as a nucleus
Binding energy is defined as:
The energy required to break a nucleus into its constituent protons and neutrons
Energy and mass are proportional, so, the total energy of a nucleus is less than the sum of the energies of its constituent nucleons
The formation of a nucleus from a system of isolated protons and neutrons is therefore an exothermic reaction - meaning that it releases energy
This can be calculated using the equation:
E = Δmc2
Exam Tip
Avoid describing the binding energy as the energy stored in the nucleus – this is not correct – it is energy that must be put into the nucleus to pull it apart.
Binding Energy per Nucleon
In order to compare nuclear stability, it is more useful to look at the?binding energy per nucleon
The binding energy per nucleon is defined as:
The binding energy of a nucleus divided by the number of nucleons in the nucleus
A higher binding energy per nucleon indicates a higher stability
In other words, it requires more energy to pull the nucleus apart
Iron (A = 56) has the highest binding energy per nucleon, which makes it the most stable of all the elements
By plotting a graph of binding energy per nucleon against nucleon number, the stability of elements can be inferred
Key Features of the Graph
At low values of A:
Nuclei tend to have a lower binding energy per nucleon, hence, they are generally less stable
This means the lightest elements have weaker electrostatic forces and are the most likely to undergo?fusion
Helium (4He), carbon (12C) and oxygen (16O) do not fit the trend
Helium-4 is a particularly stable nucleus hence it has a high binding energy per nucleon
Carbon-12 and oxygen-16 can be considered to be three and four helium nuclei, respectively, bound together
At high values of A:
The general binding energy per nucleon is high and gradually decreases with A
This means the heaviest elements are the most unstable and likely to undergo?fission
Step 3: ???????????Calculate the binding energy per nucleon
Step 4:??????????? Convert to MeV
J → eV: divide by 1.6 × 10-19
eV → MeV: divide by 106
Exam Tip
Checklist on what to include (and what not to include) in an exam question asking you to draw a graph of binding energy per nucleon against nucleon number:
You will be expected to draw the best fit curve AND a cross to show the anomaly that is helium
Do not begin your curve at A = 0, this is not a nucleus!
Make sure to correctly label both axes AND units for binding energy per nucleon
You will be expected to include numbers on the axes, mainly at the peak to show the position of iron (56Fe)