Reactions of Group 2 Oxides, Hydroxides & Carbonates
Reactions of Group 2 oxides with water
All Group 2 oxides are?basic, except for BeO which is?amphoteric?(it can act both as an acid and base)
Group 2 oxides react water to form?alkaline?solutions which get more?alkaline?going down the group
Group 2 oxide reactions with water table
Remember that:
oxide + water → hydroxide
And that calcium hydroxide is also called?limewater
Reactions of Group 2 metals with acid
The Group 2 metals will react with dilute acids to form?colourless solutions of metal salts
For example, they will form colourless solutions of metal chlorides if reacted with hydrochloric acid
When metals react with an acid, the by-product of this reaction is hydrogen gas
Group 2 metal element reactions with dilute acids table
When some of Group 2 metals react with sulfuric acid rather than hydrochloric, an insoluble sulfate forms
Going down the group, the Group 2 sulfates become less and less soluble
Calcium sulfate is sparingly soluble, but strontium sulfate and barium sulfate are insoluble
Reactions of Group 2 oxides with acid
Group 2 sulfates also form when a Group 2 oxide is reacted with an acid
The?insoluble sulfates?form at the?surface?of the oxide, which means that the solid oxide beneath it can’t react with the acid
This can be prevented to an extent by using the oxide in?powder?form and?stirring, in which case neutralisation can take place
Remember that:
oxide + dilute hydrochloric acid → salt + water
oxide + dilute sulfuric acid → sulfate + water
Reactions of group 2 hydroxides
The Group 2 metal hydroxides form?colourless solutions of metal chlorides?when they react with a dilute acid
The sulfates decrease in?solubility?going down the group (barium sulfate is an insoluble white precipitate)
Group 2 hydroxide reactions with dilute acids table
Remember that:
hydroxide + dilute acid → salt + water
hydroxide + dilute sulfuric acid → sulfate + water
Reactions of group 2 carbonates
All Group 2 carbonates (except for?BeCO3) are?insoluble in water
All Group 2 carbonates will form?soluble chloride salts,?water and carbon dioxide gas when reacted with dilute hydrochloric acid
The carbonates of Ca, Sr and Ba form as an?insoluble sulfate layer?on their solid carbonates which?stops?any further reaction after the initial bubbling (effervescence) of carbon dioxide gas?is seen
Group 2 carbonate reactions with dilute acids
Remember that:
carbonate + dilute hydrochloric acid → salt + water + carbon dioxide